| Champion | Won At | Date Won | Date Lost | Reign Duration | |
| The Educator | Fresh! | 05/07/05 | 23/08/05 | 51 days | |
| Stole the title belt on 5 July 2005, along with the Frontier one. Reign would eventually be made official by David "Pearl" Harber, with a compromise of losing the Frontier title. | |||||
| Steven Xandrous | Fresh! | 23/08/05 | 13/09/05 | 21 days | |
| Red Rock | Fresh! | 13/09/05 | 01/11/05 | 49 days | |
| Jack Murphy | Fresh! | 01/11/05 | 29/11/05 | 28 days | |
| (vacant) | Fresh! | 29/11/05 | 24/12/05 | 25 days | |
| The Livewire title was disbanded after the Winter Warfare pay-per-view. It was reinstated by Commissioner Mike Wade in September 2006. | |||||
| Johnny Lexicon | Untouchable | 13/10/06 | 24/11/06 | 42 days | |
| AWC was closed between 24 November 2006 and 25 June 2010. All champions during the hiatus are not given Reign Duration statistics since they held the belt without officially sanctioned challenge. | |||||
| Scott Taylor | Triangles | 24/11/06 | 22/02/07 | ||
| Joshua Kosidlo | GW High Octane | 22/02/07 | |||
| Global Wrestling longtimer Joshua Kosidlo captured Scott Taylor's Livewire title (though not at the first time of asking) on worldwide pay-per-view. | |||||